Volumetric, Acoustic and Optical Properties for Binary Mixtures of Nitroethane with Chloroalkane at Temperatures between 298.15 K and 318.15 K. Comparison with Theories.

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F67985858%3A_____%2F16%3A00463362" target="_blank" >RIV/67985858:_____/16:00463362 - isvavai.cz</a>

Result on the web

<a href="http://dx.doi.org/10.1016/j.molliq.2016.08.076" target="_blank" >http://dx.doi.org/10.1016/j.molliq.2016.08.076</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.molliq.2016.08.076" target="_blank" >10.1016/j.molliq.2016.08.076</a>

Result language

angličtina

Original language name

Volumetric, Acoustic and Optical Properties for Binary Mixtures of Nitroethane with Chloroalkane at Temperatures between 298.15 K and 318.15 K. Comparison with Theories.

Original language description

In a continuation from a previous work, experimental densities, speeds of sound, and refractive indices data, for eight binary liquid mixtures of nitroethane with 1,1,2,2-tetrachloroethane, 1,1,1-trichloroethane, trichloromethane, 1,2-dichloroethane, 1,3-dichloropropane, 1,4-dichlorobutane, 1-chlorobutane and 1-chloropentane were measured in the temperature range of (298.15–318.15) K and at atmospheric pressure. From the measured data the derived properties, such as the excess molar volumes, the isentropic compressibility, the deviations in isentropic compressibility, the deviations in refractive indices, the molar refractions and the deviations in molar refractions data have been calculated. The excess properties of the binary mixtures were correlated by the Redlich–Kister type polynomials using a robust regression along the gnostic influence function. Speed of sound and isentropic compressibility data have been compared with calculated values from Jacobson free length theory (FLT), Nomoto's relation (NR), Zhang Junjie's relation (JR), Van Deal's ideal mixing relation (IMR), Impedance dependence relation (IDR) and Schaaff's collision factor theory (CFT). The ability of different theoretical (n,ρ) mixing rules (Lorentz–Lorenz, Gladstone–Dale, Arago–Biot, Edwards and Eykman) to predict the refractive indices was evaluated. The experimental and calculated results are discussed in terms of molecular interactions and structural effects between components of mixtures.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

CF - Physical chemistry and theoretical chemistry

OECD FORD branch

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Project

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Continuities

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year

2016

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Journal of Molecular Liquids

ISSN

0167-7322

e-ISSN

—

Volume of the periodical

223

Issue of the periodical within the volume

NOV 2016

Country of publishing house

NL - THE KINGDOM OF THE NETHERLANDS

Number of pages

15

Pages from-to

790-804

UT code for WoS article

000386986300095

EID of the result in the Scopus database

2-s2.0-84986295362