Anodic Deposition of Enantiopure Hexahelicene Layers.
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F67985858%3A_____%2F18%3A00492063" target="_blank" >RIV/67985858:_____/18:00492063 - isvavai.cz</a>
Alternative codes found
RIV/68378271:_____/18:00492063 RIV/61388955:_____/18:00492063 RIV/00216224:14310/18:00103383 RIV/61989592:15110/18:73588039
Result on the web
<a href="http://dx.doi.org/10.1002/celc.201800565" target="_blank" >http://dx.doi.org/10.1002/celc.201800565</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/celc.201800565" target="_blank" >10.1002/celc.201800565</a>
Alternative languages
Result language
angličtina
Original language name
Anodic Deposition of Enantiopure Hexahelicene Layers.
Original language description
Helicenes are polyaromatic compounds with chiral properties useful for many applications in optoelectronics, separation processes, chiral recognition and catalysis. Here we focused on the electrochemistry of carbo[n]helicenes (n=5,6,7) with emphasis on the formation of deposited structures (layers) onto the electrode surface. The helicenes were electrodeposited onto transparent indium tin oxide (ITO) electrodes and characterized by atomic force microscopy, UV/Vis, Raman spectroscopy and ellipsometry. Finally, the anodic deposition of P and M enantiomers of [6]helicene was performed using ITO substrates, resulting in the formation of enantiopure layers of nanometer thicknesses as confirmed by circular dichroism spectroscopy. The discovered electrosynthetic procedure opens up a new possibility for the immobilization of chiral helicene layers onto solid supports.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10401 - Organic chemistry
Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2018
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
ChemElectroChem
ISSN
2196-0216
e-ISSN
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Volume of the periodical
5
Issue of the periodical within the volume
15
Country of publishing house
DE - GERMANY
Number of pages
9
Pages from-to
2080-2088
UT code for WoS article
000440546600006
EID of the result in the Scopus database
2-s2.0-85050997699