The effect of support type on promotion of activity and selectivity of Mo, CoMo, and NiMo sulfides in parallel hydrodeoxygenation of octanoic acid and hydrodesulfurization of benzothiophene.
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F67985858%3A_____%2F19%3A00505304" target="_blank" >RIV/67985858:_____/19:00505304 - isvavai.cz</a>
Result on the web
<a href="http://hdl.handle.net/11104/0296825" target="_blank" >http://hdl.handle.net/11104/0296825</a>
DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
The effect of support type on promotion of activity and selectivity of Mo, CoMo, and NiMo sulfides in parallel hydrodeoxygenation of octanoic acid and hydrodesulfurization of benzothiophene.
Original language description
The basic and amphoteric oxides MgO and Al2O3, ZrO2 do not lead to highly active NiMo catalysts presumably due to low hydrothermal stability during HDO. The most active catalysts represented NiMo sulfides supported on TiO2 and C, which yielded exclusively linear hydrocarbons by the HDO reaction. Furthermore, the NiMo/TiO2 was the most selective catalyst from the studied NiMo phases to n-octadecane, the product of octanoic acid hydrogenolysis: Pronounced isomerization and cracking activity during HDO was observed over NiMo/SiO2-Al2O3 catalyst.
Czech name
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Czech description
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Classification
Type
O - Miscellaneous
CEP classification
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OECD FORD branch
10403 - Physical chemistry
Result continuities
Project
<a href="/en/project/GA17-22490S" target="_blank" >GA17-22490S: Novel Preparation of Catalysts for Key Hydrotreating Reactions</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2019
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů