Thermal properties of novel oligoether-substituted ionic liquids and the influence of alkyl-substituent isomery
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F67985858%3A_____%2F20%3A00523744" target="_blank" >RIV/67985858:_____/20:00523744 - isvavai.cz</a>
Result on the web
<a href="http://hdl.handle.net/11104/0308041" target="_blank" >http://hdl.handle.net/11104/0308041</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.fluid.2020.112561" target="_blank" >10.1016/j.fluid.2020.112561</a>
Alternative languages
Result language
angličtina
Original language name
Thermal properties of novel oligoether-substituted ionic liquids and the influence of alkyl-substituent isomery
Original language description
This paper is a continuation of a study focused on thermodynamic properties of isomeric andquasi-isomeric ionic liquids. In this work 5 novel ionic liquids were synthesized, namely 1-(2-(2-ethoxyethoxy)ethyl)-3-alkylimidazolium bis(trifluoromethylsulfonyl)imides, where alkyl stands for different C5sub-stituents. These species were characterized as to their isobaric molar heat capacity and thermal stability.The results are discussed with respect to different substituent isomerism and compared with data fromour previous work (Rotrekl, Fluid Phase Equilib. 2017) that reported on a similar group of isomeric ionicliquids, namely 1-butyl-3-alkylimidazolium bis(trifluoromethylsulfonyl)imides. Data analysis of theexperimental heat capacites was carried out using a non-statistical approach of the mathematicalgnostics. The conclusions drawn from the present work bring an insight into thefine structure-propertyrelationship which is useful in the development of predictive tools as well as it direct applications such asin energy storage or thermalfluids development.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
20303 - Thermodynamics
Result continuities
Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2020
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Fluid Phase Equilibria
ISSN
0378-3812
e-ISSN
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Volume of the periodical
514
Issue of the periodical within the volume
JUN 15
Country of publishing house
NL - THE KINGDOM OF THE NETHERLANDS
Number of pages
6
Pages from-to
112561
UT code for WoS article
000526396100011
EID of the result in the Scopus database
2-s2.0-85082017670