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Remediation of brownfields contaminated by organic compounds and heavy metals: a bench-scale test of a sulfur/vermiculite sorbent for mercury vapor removal.

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F67985858%3A_____%2F20%3A00533656" target="_blank" >RIV/67985858:_____/20:00533656 - isvavai.cz</a>

  • Result on the web

    <a href="http://hdl.handle.net/11104/0311984" target="_blank" >http://hdl.handle.net/11104/0311984</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1007/s11356-020-10696-1" target="_blank" >10.1007/s11356-020-10696-1</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Remediation of brownfields contaminated by organic compounds and heavy metals: a bench-scale test of a sulfur/vermiculite sorbent for mercury vapor removal.

  • Original language description

    In this study, we report for the first time a novel type of sorbent that can be used for mercury adsorption from the air-based off-gasses-vermiculite impregnated with alkali polysulfides and thiosulfates. In contrast to other sorbents, vermiculite exhibits superior thermal stability in air and low adsorption capacity for organic vapors. This allows for a more favorable design of the soil remediation unit-direct coupling of thermal desorber with catalytic oxidizer using air as a carrier gas. In the bench-scale test at 180 degrees C, the sulfur/vermiculite sorbent exhibited significantly higher efficiency for the adsorption of mercury vapor from the off-gasses than the commercial sulfur/activated carbon sorbent at its highest operating temperature (120 degrees C). The average mercury concentration in the adsorber off-gas decreased from 1.634 mg/m(3) for the sulfur/activated carbon to 0.008 mg/m(3)achieved with impregnated vermiculite. The total concentration of organic compounds in the soil after thermal desorption was below the detection limit of the employed analytical method.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    20402 - Chemical process engineering

Result continuities

  • Project

    <a href="/en/project/TA04020700" target="_blank" >TA04020700: Decontamination of brownfields extensively contaminated by organic compounds and heavy metals</a><br>

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2020

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Environmental Science and Pollution Research

  • ISSN

    0944-1344

  • e-ISSN

  • Volume of the periodical

    27

  • Issue of the periodical within the volume

    33

  • Country of publishing house

    DE - GERMANY

  • Number of pages

    7

  • Pages from-to

    42182-42188

  • UT code for WoS article

    000566047600008

  • EID of the result in the Scopus database

    2-s2.0-85090300730