Calcination Temperature on N2O Conversion in the Presence of H2O and NOx

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F67985858%3A_____%2F20%3A00540440" target="_blank" >RIV/67985858:_____/20:00540440 - isvavai.cz</a>

Result on the web

<a href="http://dx.doi.org/10.3390/catal10101134" target="_blank" >http://dx.doi.org/10.3390/catal10101134</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.3390/catal10101134" target="_blank" >10.3390/catal10101134</a>

Result language

angličtina

Original language name

Calcination Temperature on N2O Conversion in the Presence of H2O and NOx

Original language description

The effect of calcination temperature (500-700 degrees C) on physico-chemical properties and catalytic activity of 2 wt. % K/Co-Mn-Al mixed oxide for N2O decomposition was investigated. Catalysts were characterized by inductively coupled plasma spectroscopy (ICP), X-ray powder diffraction (XRD), temperature-programmed reduction by hydrogen (TPR-H-2), temperature-programmed desorption of CO2 (TPD-CO2), temperature-programmed desorption of NO (TPD-NO), X-ray photoelectron spectrometry (XPS) and N-2 physisorption. It was found that the increase in calcination temperature caused gradual crystallization of Co-Mn-Al mixed oxide, which manifested itself in the decrease in Co2+/Co3+ and Mn3+/Mn4+ surface molar ratio, the increase in mean crystallite size leading to lowering of specific surface area and poorer reducibility. Higher surface K content normalized per unit surface led to the increase in surface basicity and adsorbed NO per unit surface. The effect of calcination temperature on catalytic activity was significant mainly in the presence of NOx, as the optimal calcination temperature of 500 degrees C is necessary to ensure sufficient low surface basicity, leading to the highest catalytic activity. Observed NO inhibition was caused by the formation of surface mononitrosyl species bonded to tetrahedral metal sites or nitrite species, which are stable at reaction temperatures up to 450 degrees C and block active sites for N2O decomposition.

Czech name

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Czech description

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Type

J_imp - Article in a specialist periodical, which is included in the Web of Science database

CEP classification

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OECD FORD branch

20402 - Chemical process engineering

Project

—

Continuities

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year

2020

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Catalysts

ISSN

2073-4344

e-ISSN

—

Volume of the periodical

10

Issue of the periodical within the volume

10

Country of publishing house

CH - SWITZERLAND

Number of pages

17

Pages from-to

1134

UT code for WoS article

000583992900001

EID of the result in the Scopus database

2-s2.0-85091899998