Controlled anchoring of (phenylureido)sulfonamide-based receptor moieties: an impact of binding site multiplication on complexation properties
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F67985858%3A_____%2F21%3A00545524" target="_blank" >RIV/67985858:_____/21:00545524 - isvavai.cz</a>
Alternative codes found
RIV/60461373:22310/21:43922618 RIV/60461373:22340/21:43922618
Result on the web
<a href="https://www.mdpi.com/1420-3049/26/18/5670" target="_blank" >https://www.mdpi.com/1420-3049/26/18/5670</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.3390/molecules26185670" target="_blank" >10.3390/molecules26185670</a>
Alternative languages
Result language
angličtina
Original language name
Controlled anchoring of (phenylureido)sulfonamide-based receptor moieties: an impact of binding site multiplication on complexation properties
Original language description
The repetition of urea-based binding units within the receptor structure does not only lead to monomer properties multiplication. As confirmed by spectroscopic studies, UV-Vis and 1H-NMR in classical or competitive titration mode, the attachment to a carrier allocates the active moieties to mutual positions predetermining the function of the whole receptor molecule. Bivalent receptors form self-aggregates. Dendritic receptors with low dihydrogen phosphate loadings offer ancooperative complexation mode associated with a positive dendritic effect. In higher dihydrogen phosphate concentrations, the dendritic branches act independently and the binding mode changes to 1:1 anion: complexation site. Despite the anchoring, the dendritic receptors retain the superior efficiency and selectivity of a monomer, paving the way to recyclable receptors, desirable for economic and ecological reasons.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10401 - Organic chemistry
Result continuities
Project
<a href="/en/project/GA20-07833S" target="_blank" >GA20-07833S: New nanomaterials for anion separation</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2021
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Molecules
ISSN
1420-3049
e-ISSN
1420-3049
Volume of the periodical
26
Issue of the periodical within the volume
18
Country of publishing house
CH - SWITZERLAND
Number of pages
14
Pages from-to
5670
UT code for WoS article
000701842500001
EID of the result in the Scopus database
2-s2.0-85115403195