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Optically active polyimides with different thermal histories of their preparation

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F67985858%3A_____%2F22%3A00559219" target="_blank" >RIV/67985858:_____/22:00559219 - isvavai.cz</a>

  • Alternative codes found

    RIV/60461373:22310/22:43924226 RIV/60461373:22340/22:43924226

  • Result on the web

    <a href="https://hdl.handle.net/11104/0332631" target="_blank" >https://hdl.handle.net/11104/0332631</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1002/chir.23476" target="_blank" >10.1002/chir.23476</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Optically active polyimides with different thermal histories of their preparation

  • Original language description

    Optically active linear polyimides and hyperbranched poly (amic acid-imide) were prepared by using procedures varying in particular in the maximum temperature employed in their synthesis. The two types of linear polyimides were based on 4,4 '-(hexafluoroisopropylidene)diphthalic anhydride and 1,2-diaminocylohexane enantiomers or 4,4 '-(hexafluoroisopropylidene)diphthalic anhydride and 2,2 '-diamino-1,1 '-binaphthalene enantiomers. The amine-terminated hyperbranched poly (amic acid-imide) was prepared from 4,4 '-(hexafluoroisopropylidene)diphthalic anhydride and 4,4 ',4 ''-triaminotriphenylmethane, and its end groups were modified with the chiral selectors N-acetyl-D-phenylalanine or N-acetyl-L-phenylalanine. The final structure of the products was analyzed by IR spectroscopy, and their optical activity was evaluated and confirmed by polarimetry or circular dichroism.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    20402 - Chemical process engineering

Result continuities

  • Project

    <a href="/en/project/GA20-06264S" target="_blank" >GA20-06264S: Separation of Enantiomers by Chiral Membranes: Experiment and Simulations</a><br>

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2022

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Chirality

  • ISSN

    0899-0042

  • e-ISSN

    1520-636X

  • Volume of the periodical

    34

  • Issue of the periodical within the volume

    8

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    11

  • Pages from-to

    1151-1161

  • UT code for WoS article

    000805146200001

  • EID of the result in the Scopus database

    2-s2.0-85131201558