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Carbon-carbon coupling of primary bio-alcohols over solid chemo-catalysts. TN02000044/1-V43

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F67985858%3A_____%2F24%3A00597999" target="_blank" >RIV/67985858:_____/24:00597999 - isvavai.cz</a>

  • Result on the web

    <a href="https://hdl.handle.net/11104/0355780" target="_blank" >https://hdl.handle.net/11104/0355780</a>

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Carbon-carbon coupling of primary bio-alcohols over solid chemo-catalysts. TN02000044/1-V43

  • Original language description

    The first aim of our work is to investigate chemo-catalysts in terms of their activity and selectivity in carbon-carbon coupling of ethanol and/or butanol in laboratory continuous-flow reactors. Basic high-surface-area MgO (300 m2g−1) is emphasized due to its low toxicity and easy recycling. This MgO and its chemo-catalytic properties are modified with activated carbon and compared with a conventional chemo-catalyst of aldol condensation reaction and with selected alkali, alkaline earth, lanthanide, and transition metal oxide chemo-catalysts. The second aim of our work is to investigate the selectivity of the transformation of ethanol to butanol also in terms of techno-economic process analysis. The comprehensive understanding of the first step transformation during the C-C coupling of ethanol to butanol provides realistic insight into possibilities of utilizing of biomass for platform chemicals and liquid bio-fuels.

  • Czech name

  • Czech description

Classification

  • Type

    O - Miscellaneous

  • CEP classification

  • OECD FORD branch

    20402 - Chemical process engineering

Result continuities

  • Project

    <a href="/en/project/TN02000044" target="_blank" >TN02000044: Biorefining and circular economy for sustainability</a><br>

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2024

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů