Optical properties of As2S3 layers deposited from solutions obtained by chemical reaction

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F67985882%3A_____%2F18%3A00499880" target="_blank" >RIV/67985882:_____/18:00499880 - isvavai.cz</a>

Result on the web

<a href="http://dx.doi.org/10.1007/s10971-018-4754-3" target="_blank" >http://dx.doi.org/10.1007/s10971-018-4754-3</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1007/s10971-018-4754-3" target="_blank" >10.1007/s10971-018-4754-3</a>

Result language

angličtina

Original language name

Optical properties of As2S3 layers deposited from solutions obtained by chemical reaction

Original language description

This paper deals with three approaches for the preparation of arsenic sulfide layers from solutions. First approach employs arsenic sulfide solutions obtained by dissolving powder of arsenic sulfide glass in n-propylamine. Second approach, a novel one, employs amorphous arsenic sulfide precipitated by chemical reaction of arsenic trichloride and ammonium sulfide. The precipitate was dissolved in n-propylamine. Third original approach relays on the same chemical reaction carried out in a mixture of n-propylamine and water that prevents the precipitation. By using all the approaches input arsenic sulfide solutions with a concentration of 0.33 mol/l were fabricated and applied onto glass slides by dip-coating method with withdrawing velocities of 50, 100, 200, and 250 mm/min. Applied layers dried in vacuum at 60 degrees C for 1 h and thermally treated at 180 degrees C for 30 s were characterized by optical and atomic force microscopy as well as by transmission spectroscopy in a wavelength range of 300-2500 nm. Refractive indices, thicknesses and band gaps were estimated from measured spectra. A maximum refractive index of about 2.15 at 600 nm and thicknesses up to 220 nm were determined on layers fabricated from input solutions obtained by dissolving of arsenic sulfide glass. Arsenic sulfide layers prepared on the basis of the arsenic sulfide precipitation exhibit refractive indices up around 1.90 and thicknesses up to 410 nm. Photonic band gap values on a level of 2.2 eV have been determined on these layers. On the other hands, composite layers prepared by reaction of arsenic trichloride and ammonium sulfide in the solution of n-propylamine and water exhibited low transparencies, refractive indices around 1.7 and thicknesses of about 2 mu m

Czech name

—

Czech description

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Type

J_imp - Article in a specialist periodical, which is included in the Web of Science database

CEP classification

—

OECD FORD branch

20201 - Electrical and electronic engineering

Project

<a href="/en/project/GA16-10019S" target="_blank" >GA16-10019S: Bragg fibers for delivery of laser radiation in a spectral region 1900-2300 nm</a><br>

Continuities

P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year

2018

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Journal of Sol-Gel Science and Technology

ISSN

0928-0707

e-ISSN

—

Volume of the periodical

87

Issue of the periodical within the volume

3

Country of publishing house

US - UNITED STATES

Number of pages

8

Pages from-to

696-703

UT code for WoS article

000442736500020

EID of the result in the Scopus database

2-s2.0-85050942558