Electrical and Dielectric Properties of Sb2O3-PbCl2-AgCl Glass System
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F67985891%3A_____%2F21%3A00546025" target="_blank" >RIV/67985891:_____/21:00546025 - isvavai.cz</a>
Alternative codes found
RIV/60461373:22310/21:43923522
Result on the web
<a href="https://link-springer-com.ezproxy.lib.cas.cz/article/10.1134%2FS1023193521070041" target="_blank" >https://link-springer-com.ezproxy.lib.cas.cz/article/10.1134%2FS1023193521070041</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1134/S1023193521070041" target="_blank" >10.1134/S1023193521070041</a>
Alternative languages
Result language
angličtina
Original language name
Electrical and Dielectric Properties of Sb2O3-PbCl2-AgCl Glass System
Original language description
Electrical and dielectric properties of ternary glasses in the Sb2O3-PbCl2-AgCl system were investigated across a broad temperature and frequency range. The studied glass system is interesting since it possesses a high ionic conductivity. The (Sb2O3)(x)-(PbCl2)(100y)(-)(x)-(AgCl)(y) glasses were prepared by melt-quenching method from high purity components. Different batches of these glasses were investigated with varying molar content of both Sb2O3 (45 <= x <= 70 mol %) and AgCl (5 <= y <= 25 mol %). The colour of the prepared chloro-antimonite glasses varies between yellow and brown. The glass transition temperature (T-g) decreases with increasing AgCl concentrations. DC and AC electrical conductivities and complex electrical modulus were measured across a temperature range from room temperature up to 200 degrees C and across a frequency range between 0.2 and 10(5) Hz. The dependence of DC conductivity on temperature follows the so-called Arrhenius-like equation. The DC conductivity at constant temperature significantly increases with increasing AgCl or PbCl2 content. It was found that the activation energy of conduction process decreases with the substitution of PbCl2 by AgCl from 1 eV down to 0.56 eV for (Sb2O3)(50)-(PbCl2)(45)-(AgCl)(5) and (Sb2O3)(50)-(PbCl2)(25)-(AgCl)(25), respectively. The influence of the composition on the AC conductivity of the investigated glasses is also discussed.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
20504 - Ceramics
Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2021
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Russian Journal of Electrochemistry
ISSN
1023-1935
e-ISSN
1608-3342
Volume of the periodical
57
Issue of the periodical within the volume
7
Country of publishing house
US - UNITED STATES
Number of pages
7
Pages from-to
681-687
UT code for WoS article
000680909500001
EID of the result in the Scopus database
2-s2.0-85112020593