Radii of Redox Components from Absolute Redox Potentials Compared with Covalent and Aqueous Ionic Radii

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68081707%3A_____%2F10%3A00440916" target="_blank" >RIV/68081707:_____/10:00440916 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1002/elan.200900503" target="_blank" >http://dx.doi.org/10.1002/elan.200900503</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/elan.200900503" target="_blank" >10.1002/elan.200900503</a>

Result language
angličtina
Original language name
Radii of Redox Components from Absolute Redox Potentials Compared with Covalent and Aqueous Ionic Radii
Original language description
Aqueous standard potentials, referred to that of the SHE as zero, were recently shown to vary linearly with gaseous ionization potentials, with the absolute potential of SHE as the intercept. This enabled arriving at the absolute redox potentials of elements. Here, the distances between the oxidized and reduced forms in aqueous solutions have been evaluated. From the linear dependence of these distances on the covalent radii of atoms, the radii of the redox components have been obtained. The latter alsovary linearly with the aqueous ionic radii estimated earlier from ion-water distances, and indicate the presence of aqueous molecular anions.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
BO - Biophysics
OECD FORD branch
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Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2010
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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