Capillary-column supercritical fluid chromatography as a route to solute partition coefficients in ionic liquidCO2 systems: feasibility study.
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68081715%3A_____%2F03%3A25033009" target="_blank" >RIV/68081715:_____/03:25033009 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Alternative languages
Result language
angličtina
Original language name
Capillary-column supercritical fluid chromatography as a route to solute partition coefficients in ionic liquidCO2 systems: feasibility study.
Original language description
Combination of a room-temperature ionic liquid (RTIL) and supercritical carbon dioxide provides a green alternative to conventional reaction media/solvent systems comprising volatile organic solvents. A typical application of an RTILCO2 system would involve a reaction in the RTIL environment, and a subsequent extraction of the reactants and products from the RTIL with supercritical CO2. For both fundamental understanding and process utilisation of such a procedure, high-pressure partition coefficients are necessary of the substances concerned between both phases in the RTILCO2 system. Supercritical fluid chromatography (SFC) with the RTIL as the stationary liquid phase and CO2 as the mobile-phase fluid presents a convenient and inexpensive route to thepartition coefficients, at least in low-volatility solutes. In this contribution, we report the results of a feasibility study in naphthalene1-butyl-3-methylimidazolium hexafluorophosphateCO2 system.
Czech name
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Czech description
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Classification
Type
D - Article in proceedings
CEP classification
CF - Physical chemistry and theoretical chemistry
OECD FORD branch
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Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2003
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Article name in the collection
Proceedings of the 6th International Symposium on Supercritical Fluids.
ISBN
2-905-267-3702
ISSN
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e-ISSN
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Number of pages
6
Pages from-to
711-716
Publisher name
International Society for the Advancement of Supercritical Fluids
Place of publication
Vandoeuvre
Event location
Versailles [FR]
Event date
Apr 28, 2003
Type of event by nationality
WRD - Celosvětová akce
UT code for WoS article
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