Time-dependent growth of silica shells on CdTe quantum dots
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68081715%3A_____%2F18%3A00491812" target="_blank" >RIV/68081715:_____/18:00491812 - isvavai.cz</a>
Alternative codes found
RIV/00216224:14740/18:00103164 RIV/00216305:26620/18:PU128229
Result on the web
<a href="http://dx.doi.org/10.3390/nano8060439" target="_blank" >http://dx.doi.org/10.3390/nano8060439</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.3390/nano8060439" target="_blank" >10.3390/nano8060439</a>
Alternative languages
Result language
angličtina
Original language name
Time-dependent growth of silica shells on CdTe quantum dots
Original language description
The purpose of this study is to investigate the time dependent growth of silica shells on CdTe quantum dots to get their optimum thicknesses for practical applications. The core/shell structured silica-coated CdTe quantum dots (CdTe/SiO2 QDs) were synthesized by the Strober process, which used CdTe QDs co-stabilized by mercaptopropionic acid. The coating procedure used silane primer (3-mercaptopropyltrimethoxysilane) in order to make the quantum dots (QDs) surface vitreophilic. The total size of QDs was dependent on both the time of silica shell growth in the presence of sodium silicate, and on the presence of ethanol during this growth. The size of particles was monitored during the first 72 h using two principally different methods: Dynamic Light Scattering (DLS), and Scanning Electron Microscopy (SEM). The data obtained by both methods were compared and reasons for differences discussed. Without ethanol precipitation, the silica shell thickness grew slowly and increased the nanoparticle total size from approximately 23 nm up to almost 30 nm (DLS data), and up to almost 60 nm (SEM data) in three days. During the same time period but in the presence of ethanol, the size of CdTe/SiO2 QDs increased more significantly: up to 115 nm (DLS data) and up to 83 nm (SEM data). The variances occurring between silica shell thicknesses caused by different methods of silica growth, as well as by different evaluation methods, were discussed.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10406 - Analytical chemistry
Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2018
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Nanomaterials
ISSN
2079-4991
e-ISSN
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Volume of the periodical
8
Issue of the periodical within the volume
6
Country of publishing house
CH - SWITZERLAND
Number of pages
9
Pages from-to
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UT code for WoS article
000436505200084
EID of the result in the Scopus database
2-s2.0-85048639279