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Catalytic effect of Ni, Mg2Ni and Mg2NiH4 upon hydrogen desorption from MgH2

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68081723%3A_____%2F11%3A00369588" target="_blank" >RIV/68081723:_____/11:00369588 - isvavai.cz</a>

  • Result on the web

    <a href="http://dx.doi.org/10.1016/j.ijhydene.2011.07.133" target="_blank" >http://dx.doi.org/10.1016/j.ijhydene.2011.07.133</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1016/j.ijhydene.2011.07.133" target="_blank" >10.1016/j.ijhydene.2011.07.133</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Catalytic effect of Ni, Mg2Ni and Mg2NiH4 upon hydrogen desorption from MgH2

  • Original language description

    MgH2 is a perspective hydrogen storage material whose main advantage is a relatively high hydrogen storage capacity (theoretically, 7.6 wt.% H2). This compound, however, shows poor hydrogen desorption kinetics. Much effort was devoted in the past to finding possible ways of enhancing hydrogen desorption rate from MgH2, which would bring this material closer to technical applications. One possible way is catalysis of hydrogen desorption. This paper investigates separate catalytic effects of Ni, Mg2Ni andMg2NiH4 on the hydrogen desorption characteristics of MgH2. It was observed that the catalytic efficiency of Mg2NiH4 was considerably higher than that of pure Ni and non-hydrated intermetallic Mg2Ni. The Mg2NiH4 phase has two low-temperature modifications below 508 K: un-twinned phase LT1 and micro-twinned phase LT2. LT1 was observed to have significantly higher catalytic efficiency than LT2.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    JG - Metallurgy, metal materials

  • OECD FORD branch

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2011

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    International Journal of Hydrogen Energy

  • ISSN

    0360-3199

  • e-ISSN

  • Volume of the periodical

    36

  • Issue of the periodical within the volume

    21

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    7

  • Pages from-to

    13614-13620

  • UT code for WoS article

    000296208800030

  • EID of the result in the Scopus database