Modelling for hydrogen diffusion in metals with traps revisited

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68081723%3A_____%2F12%3A00369684" target="_blank" >RIV/68081723:_____/12:00369684 - isvavai.cz</a>
Result on the web
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DOI - Digital Object Identifier
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Result language
angličtina
Original language name
Modelling for hydrogen diffusion in metals with traps revisited
Original language description
A rigorous concept for diffusion of hydrogen is presented that allows for the role of trapping and/or hydrostatic stress. Nonlinear partial differential equations for the concentration of freely diffusing hydrogen in the lattice and for the total concentration of hydrogen both in the lattice and traps are derived. A generalized chemical diffusion coefficient can be deduced and is compared with reported relations from the literature. Simulation results are presented for different amounts of traps and their different energetic levels (depths), both for hydrogen concentration profiles and the total amount of hydrogen in the case of charging or discharging a cylindrical specimen. A significant charging/discharging asymmetry occurs for high hydrogen concentrations and high amounts of traps of sufficient depth. Comparisons of the chemical diffusion coefficient with experimental results from the literature are also presented.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
BJ - Thermodynamics
OECD FORD branch
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Project
<a href="/en/project/GAP204%2F10%2F1784" target="_blank" >GAP204/10/1784: Modelling of diffusional phase transformations in multicomponent systems with multiple stoichiometric phases</a><br>
Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year
2012
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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