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Synthesis and crystallization mechanism of europium-titanate Eu2Ti2O7

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68081723%3A_____%2F14%3A00428391" target="_blank" >RIV/68081723:_____/14:00428391 - isvavai.cz</a>

  • Alternative codes found

    RIV/61388980:_____/14:00428391 RIV/67985882:_____/14:00428391

  • Result on the web

    <a href="http://dx.doi.org/10.1016/j.jcrysgro.2013.12.045" target="_blank" >http://dx.doi.org/10.1016/j.jcrysgro.2013.12.045</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1016/j.jcrysgro.2013.12.045" target="_blank" >10.1016/j.jcrysgro.2013.12.045</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Synthesis and crystallization mechanism of europium-titanate Eu2Ti2O7

  • Original language description

    The synthesis of nanocrystalline europium-titanate pyrochlore Eu2Ti2O7 by a generic sol gel approach is presented. The size of the formed nanocrystals was tailored from 20 nm to 100 nm. The nucleation process and the crystallization mechanism were studied. The activation energies of the crystallization process and crystal growth were calculated. It was found; from the calculated Avrami0s parameters; that the crystallization process starts by homogenous nucleation followed by three dimensional growth. The activation energies of the crystallization process were about 700 kJ mol 1. The energy of nanocrystal growth was 26.573.9 kJ mol 1. The results present fundamental information about the crystallization behavior of RE2Ti2O7 prepared by the condensationof titanium alkoxides with inorganic salts of rareearth elements.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    BJ - Thermodynamics

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/GAP102%2F10%2F2139" target="_blank" >GAP102/10/2139: Preparation and properties of silica-based optical glasses containing rare-earth- and chromium -doped nano-particles</a><br>

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2014

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Journal of Crystal Growth

  • ISSN

    0022-0248

  • e-ISSN

  • Volume of the periodical

  • Issue of the periodical within the volume

    391

  • Country of publishing house

    NL - THE KINGDOM OF THE NETHERLANDS

  • Number of pages

    8

  • Pages from-to

    25-32

  • UT code for WoS article

    000335770700005

  • EID of the result in the Scopus database