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Effect of pressure on magnetic properties of mixed ferroferrimagnet(Ni0.38Mn0.62)3[Cr(CN)6]2.zH2O

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F10%3A00347867" target="_blank" >RIV/68378271:_____/10:00347867 - isvavai.cz</a>

  • Result on the web

  • DOI - Digital Object Identifier

Alternative languages

  • Result language

    angličtina

  • Original language name

    Effect of pressure on magnetic properties of mixed ferroferrimagnet(Ni0.38Mn0.62)3[Cr(CN)6]2.zH2O

  • Original language description

    We present the results of magnetization measurements performed on the ferro?ferrimagnetic Ni0.38Mn0.62)3[Cr(CN)6]2.zH2O molecule?based magnet under pressures up to 0.8 GPa.Both antiferromagnetic JAF and ferromagnetic interaction JF are present in this magnet and temperature dependence of magnetization ?(T) exhibits the compensation temperature Tcomp at which the sign of the magnetization is reversed.Our results indicate that JAF dominates.The Curie temperature TC of the magnet increases with applied pressure, dTC/dp = 10.6 KGPa-1, due to strengthened JAF.The increase of the JAF is attributed to the enhanced value of the single electron overlapping integral S and the energy gap ? of the mixed molecular orbitals t2g (Mn2+) and t2g (CrIII) induced by pressure.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    BM - Solid-state physics and magnetism

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/IAA100100632" target="_blank" >IAA100100632: Interface in nanogranular systems ? the effect of external high pressures on the magnetic and magnetotransport properties</a><br>

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)<br>Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2010

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Journal of Physics: Conference Series

  • ISSN

    1742-6588

  • e-ISSN

  • Volume of the periodical

    200

  • Issue of the periodical within the volume

    2

  • Country of publishing house

    GB - UNITED KINGDOM

  • Number of pages

    4

  • Pages from-to

  • UT code for WoS article

  • EID of the result in the Scopus database