Synthesis and characterization of single crystals of the layered copper hydroxide acetate Cu2(OH)3(CH3COO)H2O
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F11%3A00368900" target="_blank" >RIV/68378271:_____/11:00368900 - isvavai.cz</a>
Alternative codes found
RIV/61388980:_____/11:00368900
Result on the web
<a href="http://dx.doi.org/10.1002/crat.201100262" target="_blank" >http://dx.doi.org/10.1002/crat.201100262</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/crat.201100262" target="_blank" >10.1002/crat.201100262</a>
Alternative languages
Result language
angličtina
Original language name
Synthesis and characterization of single crystals of the layered copper hydroxide acetate Cu2(OH)3(CH3COO)H2O
Original language description
Single-crystals of the layered copper hydroxide acetate Cu2(OH)3(CH3COO)H2O were synthesized by heating copper acetate solution at 60°C. The standard synthesis of the title compound based on slow titration of copper acetate solution with NaOH yielded materials with worse morphology and an additional phase present. The obtained products were characterised with powder X-ray diffraction, high temperature powder X-ray diffraction, scanning electron microscopy and infrared spectroscopy. The crystal structurewas determined from single-crystal X-ray diffraction data, collected both at 120 K and at 293 K. The title compound crystallizes in the monoclinic botallackite-type layered structure, with the lattice parameters a = 5.5776(3) ?, b = 6.0733(2) ?, c = 18.5134(8) ?, beta = 91.802(4)° and a = 5.5875(4)?, b = 6.0987(4)?, c = 18.6801(10)?, beta = 91.934(5)° for 120 K and for 293 K, respectively. Acetate groups and water molecules are interlayered between corrugated sheets of edge-sharing CuO6
Czech name
—
Czech description
—
Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CA - Inorganic chemistry
OECD FORD branch
—
Result continuities
Project
—
Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2011
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Crystal Research and Technology
ISSN
0232-1300
e-ISSN
—
Volume of the periodical
46
Issue of the periodical within the volume
10
Country of publishing house
DE - GERMANY
Number of pages
7
Pages from-to
1051-1057
UT code for WoS article
000295315900007
EID of the result in the Scopus database
—