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Antiferrodistortive phase transition in EuTiO3.

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F12%3A00380651" target="_blank" >RIV/68378271:_____/12:00380651 - isvavai.cz</a>

  • Alternative codes found

    RIV/00025798:_____/12:00000582 RIV/00216305:26620/12:PU99450

  • Result on the web

    <a href="http://dx.doi.org/10.1103/PhysRevB.86.054112" target="_blank" >http://dx.doi.org/10.1103/PhysRevB.86.054112</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1103/PhysRevB.86.054112" target="_blank" >10.1103/PhysRevB.86.054112</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Antiferrodistortive phase transition in EuTiO3.

  • Original language description

    X-ray diffraction, dynamical mechanical analysis, and infrared reflectivity studies revealed an antiferrodistortive phase transition in EuTiO3 ceramics. Near 300 K, the perovskite structure changes from cubic Pm3m to tetragonal I4/mcm. Some ceramics as well as single crystals of EuTiO3 show different infrared reflectivity spectra bringing evidence of a different crystal structure. In such samples, electron diffraction revealed an incommensurate tetragonal structure with modulation wave vector q 0.38aa*.Extra phonons in samples with modulated structure are activated in the IR spectra due to folding of the Brillouin zone. We propose that defects such as Eu3+ and oxygen vacancies strongly influence the temperature of the phase transition to antiferrodistortive phase as well as the tendency to incommensurate modulation in EuTiO3.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    BM - Solid-state physics and magnetism

  • OECD FORD branch

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    Z - Vyzkumny zamer (s odkazem do CEZ)

Others

  • Publication year

    2012

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Physical Review. B

  • ISSN

    1098-0121

  • e-ISSN

  • Volume of the periodical

    86

  • Issue of the periodical within the volume

    5

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    9

  • Pages from-to

    "054112-1"-"054112-9"

  • UT code for WoS article

    000307717600001

  • EID of the result in the Scopus database