Calciodelrioite, Ca(VO3)2(H2O)4, the Ca analogue of delrioite, Sr(VO3)2(H2O)4./sub
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F12%3A00389446" target="_blank" >RIV/68378271:_____/12:00389446 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1180/minmag.2012.076.7.12" target="_blank" >http://dx.doi.org/10.1180/minmag.2012.076.7.12</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1180/minmag.2012.076.7.12" target="_blank" >10.1180/minmag.2012.076.7.12</a>
Alternative languages
Result language
angličtina
Original language name
Calciodelrioite, Ca(VO3)2(H2O)4, the Ca analogue of delrioite, Sr(VO3)2(H2O)4./sub
Original language description
Calciodelrioite, ideally Ca(VO3)2(H2O)4, is a new mineral (IMA 2012-031). It is monoclinic, I2/a, with a=14.6389(10), b=6.9591(4), c=17.052(2) A , beta=102.568(9)°, V=1695.5(3) A3 and Z=8. In the structure of calciodelrioite (refined to R1=3.14% for 1216Fo>4?F),V5+O5 polyhedra link by sharing edges to form a zigzag divanadate [VO3] chain along a, similar to that in the structure of rossite. The chains are linked via bonds to Ca atoms, which also bond to H2O groups, yielding CaO3(H2O)6 polyhedra. The Capolyhedra form a chain along b. Each of the two symmetrically independent VO5 polyhedra has two short vanadyl bonds and three long equatorial bonds. Calciodelrioite and delrioite are isostructural and are the endmembers of the series Ca-Sr. Calciodelrioite is dimorphous with rossite, which has a similar structure; however, the smaller 8-coordinate Ca site in rossite does not accommodate Sr.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
BM - Solid-state physics and magnetism
OECD FORD branch
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Result continuities
Project
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Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2012
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Mineralogical Magazine
ISSN
0026-461X
e-ISSN
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Volume of the periodical
76
Issue of the periodical within the volume
7
Country of publishing house
GB - UNITED KINGDOM
Number of pages
15
Pages from-to
2803-2817
UT code for WoS article
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EID of the result in the Scopus database
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