A novel amido?pyrophosphate Mnll chelate complex with the synthetic ligand O{P(O)[NHC(CH3)3]2}2 (L): [Mn(L)2{OC(H)N(CH3)2}2]Cl2 . 2H2O

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F13%3A00398666" target="_blank" >RIV/68378271:_____/13:00398666 - isvavai.cz</a>

Result on the web

<a href="http://dx.doi.org/10.1107/S0108270113000814" target="_blank" >http://dx.doi.org/10.1107/S0108270113000814</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1107/S0108270113000814" target="_blank" >10.1107/S0108270113000814</a>

Result language

angličtina

Original language name

A novel amido?pyrophosphate Mnll chelate complex with the synthetic ligand O{P(O)[NHC(CH3)3]2}2 (L): [Mn(L)2{OC(H)N(CH3)2}2]Cl2 . 2H2O

Original language description

The title complex is the first example of a bis-chelate amido-pyrophosphate (pyrophosphoramide) complex containing an O[P(O)(NH)2]2 fragment. Its asymmetric unit contains half of the complex dication, one chloride anion and one water molecule. The MnII atom, located on an inversion centre, is octahedrally coordinated. Structural features, such as the P O bond lengths and the planarity of the chelate ring, are compared with those of previously reported complexes with six-membered chelates involving the fragments C(O)NHP(O), (X)NP(O) [X = C(O), C(S), S(O)2 and P(O)] and O[P(O)(N)2]2. The extended structure of the title complex involves a linear aggregate mediated by hydrogen bonds, in which the chloride anion is an acceptor in two additional O?H...Cl hydrogen bonds.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

BM - Solid-state physics and magnetism

OECD FORD branch

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Project

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Continuities

Z - Vyzkumny zamer (s odkazem do CEZ)

Publication year

2013

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Acta Crystallographica. C - Crystal Structure Communications

ISSN

0108-2701

e-ISSN

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Volume of the periodical

69

Issue of the periodical within the volume

Mar

Country of publishing house

DK - DENMARK

Number of pages

4

Pages from-to

225-228

UT code for WoS article

000315648600005

EID of the result in the Scopus database

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