Structures of a novel phosphoric triamide and its organotin(IV) complex

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F13%3A00399569" target="_blank" >RIV/68378271:_____/13:00399569 - isvavai.cz</a>

Result on the web

<a href="http://dx.doi.org/10.1016/j.jorganchem.2013.08.003" target="_blank" >http://dx.doi.org/10.1016/j.jorganchem.2013.08.003</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1016/j.jorganchem.2013.08.003" target="_blank" >10.1016/j.jorganchem.2013.08.003</a>

Result language

angličtina

Original language name

Structures of a novel phosphoric triamide and its organotin(IV) complex

Original language description

A new phosphoric triamide 4-NO2C6H4NHP(O)(NC4H8O)2 (1) and its organotin(IV) complex SnCl(C6H5)3[4-NO2C6H4NHP(O)(NC4H8O)2] (2) were synthesized and characterized by NMR, IR spectroscopy and elemental analysis. The crystal structures of compounds 1 and 2were determined by X-ray crystallography. Both compounds crystallize in monoclinic crystal system with P21/n space group. The structure of 1 contains two symmetrically independent molecules while for 2 only one independent molecule is present with a five-coordinated tin(IV) in a distorted trigonal bipyramidal configuration. Strong intermolecular N -HO and N-HCl hydrogen bonds together with weak intermolecular C-HO hydrogen bonds connect molecules of 1 and 2 into 3D networks.

Czech name

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Czech description

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Type

J_x - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

CEP classification

BM - Solid-state physics and magnetism

OECD FORD branch

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Project

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Continuities

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year

2013

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Journal of Organometallic Chemistry

ISSN

0022-328X

e-ISSN

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Volume of the periodical

745

Issue of the periodical within the volume

NOV

Country of publishing house

CH - SWITZERLAND

Number of pages

7

Pages from-to

432-438

UT code for WoS article

000326112700058

EID of the result in the Scopus database

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