Use of [SbF6] - to isolate cationic copper and silver adducts with more than one ethylene on the metal center
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F13%3A00421128" target="_blank" >RIV/68378271:_____/13:00421128 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1021/om4002439" target="_blank" >http://dx.doi.org/10.1021/om4002439</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/om4002439" target="_blank" >10.1021/om4002439</a>
Alternative languages
Result language
angličtina
Original language name
Use of [SbF6] - to isolate cationic copper and silver adducts with more than one ethylene on the metal center
Original language description
A cationic tris(ethylene)copper(I) and tris(ethylene)silver(I) adduct has been isolated using hexafluoroantimonate counterion. X-ray crystallographic analysis shows that the metal atom in these adducts coordinates to three ethylene molecules in a trigonal planar fashion, forming a spoke-wheel arrangement. In [M(C2H4)3][SbF6] adducts (M = Cu, Ag, Au), the average MC distances of 2.189 ? for Cu and 2.410 ? for Ag can be compared with the corresponding distance of 2.268 ? for Au and show that the copper(I)complex has the shortest while the silver adduct displays the longest MC distances.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
BM - Solid-state physics and magnetism
OECD FORD branch
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Result continuities
Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2013
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Organometallics
ISSN
0276-7333
e-ISSN
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Volume of the periodical
32
Issue of the periodical within the volume
10
Country of publishing house
US - UNITED STATES
Number of pages
8
Pages from-to
3034-3041
UT code for WoS article
000319650300021
EID of the result in the Scopus database
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