A (3+3)-dimensional "hypercubic" oxide-ionic conductor: type II Bi2O3-Nb2O5 .
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F13%3A00421656" target="_blank" >RIV/68378271:_____/13:00421656 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1021/ja3109328" target="_blank" >http://dx.doi.org/10.1021/ja3109328</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/ja3109328" target="_blank" >10.1021/ja3109328</a>
Alternative languages
Result language
angličtina
Original language name
A (3+3)-dimensional "hypercubic" oxide-ionic conductor: type II Bi2O3-Nb2O5 .
Original language description
The high-temperature cubic form of bismuth oxide, ?-Bi2O3, is the best intermediate-temperature oxide-ionic conductor known. The most elegant way of stabilizing ?-Bi2O3 to room temperature, while preserving a large part of its conductivity, is by dopingwith higher valent transition metals to create wide solid-solutions fields with exceedingly rare and complex (3 + 3)-dimensional incommensurately modulated ?hypercubic structures. These materials remain poorly understood because no such structure has ever been quantitatively solved and refined, due to both the complexity of the problem and a lack of adequate experimental data.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
BM - Solid-state physics and magnetism
OECD FORD branch
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Result continuities
Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2013
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of the American Chemical Society
ISSN
0002-7863
e-ISSN
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Volume of the periodical
135
Issue of the periodical within the volume
17
Country of publishing house
US - UNITED STATES
Number of pages
8
Pages from-to
6477-6484
UT code for WoS article
000318469100022
EID of the result in the Scopus database
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