New rac-XP(O)(OC6H5)(NHC6H4-p- CH3) [X = N(CH3)(cyclo-C6H11) and NH(C3H5)] and rac-(C6H5CH2NH)- P(O)(OC6H5)(NH-cyclo-C6H11) mixed-amide phosphinates
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F13%3A00421726" target="_blank" >RIV/68378271:_____/13:00421726 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1107/S010827011302341X" target="_blank" >http://dx.doi.org/10.1107/S010827011302341X</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1107/S010827011302341X" target="_blank" >10.1107/S010827011302341X</a>
Alternative languages
Result language
angličtina
Original language name
New rac-XP(O)(OC6H5)(NHC6H4-p- CH3) [X = N(CH3)(cyclo-C6H11) and NH(C3H5)] and rac-(C6H5CH2NH)- P(O)(OC6H5)(NH-cyclo-C6H11) mixed-amide phosphinates
Original language description
The mixed-amide phosphinates, rac-phenyl (N-methylcyclohexylamido(ptolylamido)phosphinate, C2027HN2O2P, (I), and rac-phenyl (allylamido)(p-tolylamido)phosphinate, C16H19-N2O2P, (II), were synthesized from the racemic phosphorus? chlorine compound (R,S)-(Cl)P(O)(OC6H5)(NHC6H4-p-CH3). Furthermore, the phosphorus?chlorine compound ClP(O)-(OC6H5)(NH-cyclo-C6H11) was synthesized for the first time and used for the synthesis of rac-phenyl (benzylamido)(cyclohexylamido) phosphinate, C19H25N2O2P, (III). The strategies for the synthesis of racemic mixed-amide phosphinates are discussed. The P atom in each compound is in a distorted tetrahedral (N1)P( O)(O)(N2) environment.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
BM - Solid-state physics and magnetism
OECD FORD branch
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Result continuities
Project
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Continuities
Z - Vyzkumny zamer (s odkazem do CEZ)
Others
Publication year
2013
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Acta Crystallographica. C - Crystal Structure Communications
ISSN
0108-2701
e-ISSN
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Volume of the periodical
69
Issue of the periodical within the volume
Part 10
Country of publishing house
DK - DENMARK
Number of pages
18
Pages from-to
1181-"sub-13"
UT code for WoS article
000325288000023
EID of the result in the Scopus database
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