Dimercuration of calix[4]arenes: Novel substitution pattern in calixarene chemistry

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F14%3A00427124" target="_blank" >RIV/68378271:_____/14:00427124 - isvavai.cz</a>
Alternative codes found
RIV/60461373:22310/14:43896706 RIV/60461373:22810/14:43896706
Result on the web
<a href="http://dx.doi.org/10.1021/ol403133b" target="_blank" >http://dx.doi.org/10.1021/ol403133b</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/ol403133b" target="_blank" >10.1021/ol403133b</a>

Result language
angličtina
Original language name
Dimercuration of calix[4]arenes: Novel substitution pattern in calixarene chemistry
Original language description
A mercuration reaction of tetrapropoxycalix[4]-arene immobilized in the cone conformation gave a mixture of two dimercurated products (meta,meta and meta,para) in approximately a 1:1 ratio. Both regioisomers represent inherently chiral compounds, which makes them very attractive for design of novel receptors. As demonstrated by Pd-catalyzed arylation, the different reactivity of HgCl functions in the meta,para-disubstituted isomer opens the door for regioselective introductions of two different functional groups to achieve a substitution pattern so far unknown in calixarene chemistry.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CC - Organic chemistry
OECD FORD branch
—

Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2014
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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