Single 3d transition metal atoms on multi-layer graphene systems: electronic configurations, bonding mechanisms and role of the substrate
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F14%3A00432547" target="_blank" >RIV/68378271:_____/14:00432547 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1088/1367-2630/16/6/062001" target="_blank" >http://dx.doi.org/10.1088/1367-2630/16/6/062001</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1088/1367-2630/16/6/062001" target="_blank" >10.1088/1367-2630/16/6/062001</a>
Alternative languages
Result language
angličtina
Original language name
Single 3d transition metal atoms on multi-layer graphene systems: electronic configurations, bonding mechanisms and role of the substrate
Original language description
The electronic configurations of Fe, Co, Ni and Cu adatoms on graphene and graphite have been studied by x-ray magnetic circular dichroism and charge transfer multiplet theory. A delicate interplay between long-range interactions and local chemical bonding is found to influence the adatom equilibrium distance and magnetic moment. The results for Fe and Co are consistent with purely physisorbed species having, however, different 3d-shell occupations on graphene and graphite (dn+1 and dn, respectively). On the other hand, for the late 3d metals Ni and Cu a trend towards chemisorption is found, which strongly quenches the magnetic moment on both substrates.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
BM - Solid-state physics and magnetism
OECD FORD branch
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Result continuities
Project
<a href="/en/project/GAP108%2F11%2F0853" target="_blank" >GAP108/11/0853: Nanostructures with transition metals: Towards ab-initio material design</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2014
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
New Journal of Physics
ISSN
1367-2630
e-ISSN
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Volume of the periodical
16
Issue of the periodical within the volume
Jun
Country of publishing house
DE - GERMANY
Number of pages
11
Pages from-to
1-11
UT code for WoS article
000339083000001
EID of the result in the Scopus database
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