Mercuration of thiacalix[4]arenes in the cone and 1,3-alternate conformations

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F14%3A00435319" target="_blank" >RIV/68378271:_____/14:00435319 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1039/c4ob00799a" target="_blank" >http://dx.doi.org/10.1039/c4ob00799a</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/c4ob00799a" target="_blank" >10.1039/c4ob00799a</a>

Result language
angličtina
Original language name
Mercuration of thiacalix[4]arenes in the cone and 1,3-alternate conformations
Original language description
The first mercuration in the thiacalixarene series using thiacalix[4]arenes immobilized in the cone or 1,3-alternate conformations gave a mixture of two monomercurated regioisomers (meta and para) in approx. 4 : 1 and 2 : 1 ratios, respectively. The organomercurial intermediates show unusual solid-state behaviour, as evidenced by the formation of ?6 complexes, and can be easily transformed into halogen-substituted derivatives, so far inaccessible in thiacalixarene chemistry. This paves the way towards the synthesis of inherently chiral thiacalixarene-based receptors with an unusual substitution pattern.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
CC - Organic chemistry
OECD FORD branch
—

Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2014
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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