Kinetics of thermal decomposition and kinetics of substitution reaction of nano uranyl Schiff base complexes
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F14%3A00440548" target="_blank" >RIV/68378271:_____/14:00440548 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1002/kin.20881" target="_blank" >http://dx.doi.org/10.1002/kin.20881</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1002/kin.20881" target="_blank" >10.1002/kin.20881</a>
Alternative languages
Result language
angličtina
Original language name
Kinetics of thermal decomposition and kinetics of substitution reaction of nano uranyl Schiff base complexes
Original language description
This study focuses on the synthesis, characterization, and kinetics of substitution reaction of new uranyl Schiff base complexes prepared in a crystalline state as well as in a form of nanoparticles. The compounds were characterized by UV?vis, 1H NMR, cyclic voltammetry and X-ray crystallography. X-ray crystallography revealed coordination of the uranyl by the tetradentate Schiff base ligand and one solvent molecule, resulting in seven-coordinated uranium. The second-order rate constants at four temperatures and the activation parameters revealed an associative mechanism for all corresponding complexes. Anticancer activity of the nano uranyl Schiff base complexes against cancer cell lines (Jurkat) was also studied.
Czech name
—
Czech description
—
Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
BM - Solid-state physics and magnetism
OECD FORD branch
—
Result continuities
Project
<a href="/en/project/GAP204%2F11%2F0809" target="_blank" >GAP204/11/0809: Absorption, beam homogeneity and varying irradiated volume corrections in multidomain bulk and thin film samples.</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2014
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
International Journal of Chemical Kinetics
ISSN
0538-8066
e-ISSN
—
Volume of the periodical
46
Issue of the periodical within the volume
12
Country of publishing house
US - UNITED STATES
Number of pages
12
Pages from-to
718-729
UT code for WoS article
000344389600002
EID of the result in the Scopus database
—