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Three tetracoordinate Co(II) complexes [Co(biq)X2] (X = Cl, Br, I) with easy-plane magnetic anisotropy as field-induced single-molecule magnets

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F15%3A00456411" target="_blank" >RIV/68378271:_____/15:00456411 - isvavai.cz</a>

  • Result on the web

    <a href="http://dx.doi.org/10.1039/c5dt02827b" target="_blank" >http://dx.doi.org/10.1039/c5dt02827b</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1039/c5dt02827b" target="_blank" >10.1039/c5dt02827b</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Three tetracoordinate Co(II) complexes [Co(biq)X2] (X = Cl, Br, I) with easy-plane magnetic anisotropy as field-induced single-molecule magnets

  • Original language description

    Three mononuclear complexes [Co(biq)X2] (biq = 2,2?-biquinoline; X = Cl, Br, I) were prepared by a solvothermal method and characterized by single-crystal X-ray diffraction. In all three complexes the Co(II) atom is tetrahedrally coordinated by one biq ligand bonded in a chelate manner and two halogenido ligands. Hydrogen bonding interactions (C?H X) along with the ?? ? interactions contribute to the stability of the formed packing. Magnetic measurements as well as ab initio calculations revealed that the complexes possess a sizable easy-plane magnetic anisotropy (D > 0). They display a superparamagnetic behaviour in an applied external field that culminates between BDC = 0.2?0.3 T.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    BM - Solid-state physics and magnetism

  • OECD FORD branch

Result continuities

  • Project

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2015

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Dalton Transactions

  • ISSN

    1477-9226

  • e-ISSN

  • Volume of the periodical

    44

  • Issue of the periodical within the volume

    40

  • Country of publishing house

    GB - UNITED KINGDOM

  • Number of pages

    7

  • Pages from-to

    17565-17571

  • UT code for WoS article

    000362362500016

  • EID of the result in the Scopus database

    2-s2.0-84943568525