Three tetracoordinate Co(II) complexes [Co(biq)X2] (X = Cl, Br, I) with easy-plane magnetic anisotropy as field-induced single-molecule magnets
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F15%3A00456411" target="_blank" >RIV/68378271:_____/15:00456411 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1039/c5dt02827b" target="_blank" >http://dx.doi.org/10.1039/c5dt02827b</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/c5dt02827b" target="_blank" >10.1039/c5dt02827b</a>
Alternative languages
Result language
angličtina
Original language name
Three tetracoordinate Co(II) complexes [Co(biq)X2] (X = Cl, Br, I) with easy-plane magnetic anisotropy as field-induced single-molecule magnets
Original language description
Three mononuclear complexes [Co(biq)X2] (biq = 2,2?-biquinoline; X = Cl, Br, I) were prepared by a solvothermal method and characterized by single-crystal X-ray diffraction. In all three complexes the Co(II) atom is tetrahedrally coordinated by one biq ligand bonded in a chelate manner and two halogenido ligands. Hydrogen bonding interactions (C?H X) along with the ?? ? interactions contribute to the stability of the formed packing. Magnetic measurements as well as ab initio calculations revealed that the complexes possess a sizable easy-plane magnetic anisotropy (D > 0). They display a superparamagnetic behaviour in an applied external field that culminates between BDC = 0.2?0.3 T.
Czech name
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Czech description
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Classification
Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
BM - Solid-state physics and magnetism
OECD FORD branch
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Result continuities
Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2015
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Dalton Transactions
ISSN
1477-9226
e-ISSN
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Volume of the periodical
44
Issue of the periodical within the volume
40
Country of publishing house
GB - UNITED KINGDOM
Number of pages
7
Pages from-to
17565-17571
UT code for WoS article
000362362500016
EID of the result in the Scopus database
2-s2.0-84943568525