Crystal structure of copper(I) thiosemicarbazone complex [CuI(PPh3)(catsc)]

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F15%3A00456424" target="_blank" >RIV/68378271:_____/15:00456424 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1134/S0022476615050273" target="_blank" >http://dx.doi.org/10.1134/S0022476615050273</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1134/S0022476615050273" target="_blank" >10.1134/S0022476615050273</a>

Result language
angličtina
Original language name
Crystal structure of copper(I) thiosemicarbazone complex [CuI(PPh3)(catsc)]
Original language description
In this paper, we report the preparation of a four-coordinated copper(I) thiosemicarbazone complex [CuI(PPh3)(catsc)] from the reaction of PPh3 and catsc (3-phenylpropenalthiosemicarbazone) with CuI. The synthesized complex is characterized by elementalanalyses (CHNS) and FT-IR spectroscopy. The crystal structure of [CuI(PPh3)(catsc)] is investigated by single crystal X-ray diffraction. The catsc coordinates to the copper(I) ion as a bidentate ligand via the N and S atoms. The complex has a distorted tetrahedral coordination geometry.
Czech name
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Czech description
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Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
BM - Solid-state physics and magnetism
OECD FORD branch
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Project
<a href="/en/project/GA15-12653S" target="_blank" >GA15-12653S: Validation and Interpretation of Modulated Structures</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2015
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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