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Water interaction with hydrogenated and oxidized detonationnanodiamonds - microscopic and spectroscopic analyses

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F16%3A00458952" target="_blank" >RIV/68378271:_____/16:00458952 - isvavai.cz</a>

  • Alternative codes found

    RIV/68407700:21230/16:00302980

  • Result on the web

    <a href="http://dx.doi.org/10.1016/j.diamond.2015.08.016" target="_blank" >http://dx.doi.org/10.1016/j.diamond.2015.08.016</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1016/j.diamond.2015.08.016" target="_blank" >10.1016/j.diamond.2015.08.016</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Water interaction with hydrogenated and oxidized detonationnanodiamonds - microscopic and spectroscopic analyses

  • Original language description

    Here we report on investigation of water interaction with hydrogenated and oxidized detonation nanodiamonds (H-DNDs, O-DNDs) by means of Fourier transform infrared spectroscopy (FTIR), thermal analysis, and Kelvin probe force microscopy (KPFM). Higher water content (4.4%) as well as weaker interaction of water with H-DNDs are identified by thermal analysis. It is explained by hydrophobicity of the H-DND surface, as revealed by the analysis surface water in FTIR spectra. On the other hand, hydrophilic nature of O-DNDs leads to lower water content (3.1%) but stronger interaction with the O-DND surface. This is evidenced by as high as 300 °C desorption temperature of the surface water from O-DNDs. KPFM analysis shows that the surface-bound water can have significant screening effect on contact potential difference (CPD) of nanodiamonds (up to 510 mV) as well as on the CPD difference between H-DNDs and O-DNDs (from 50 mV to 210 mV). Nevertheless, H-DNDs exhibit always lower work function.n

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    BM - Solid-state physics and magnetism

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/GA15-01809S" target="_blank" >GA15-01809S: Study of surface-functionalized diamond nanoparticles for energy conversion</a><br>

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2016

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Diamond and Related Materials

  • ISSN

    0925-9635

  • e-ISSN

  • Volume of the periodical

    63

  • Issue of the periodical within the volume

    Mar

  • Country of publishing house

    CH - SWITZERLAND

  • Number of pages

    6

  • Pages from-to

    97-102

  • UT code for WoS article

    000371942700018

  • EID of the result in the Scopus database

    2-s2.0-84959242332