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Static and dynamic characteristics of the Cr3+ EPR spectra in the Van Vleck paramagnet TmAl3(BO3)4

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F16%3A00458954" target="_blank" >RIV/68378271:_____/16:00458954 - isvavai.cz</a>

  • Result on the web

    <a href="http://dx.doi.org/10.1007/s10853-015-9646-0" target="_blank" >http://dx.doi.org/10.1007/s10853-015-9646-0</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1007/s10853-015-9646-0" target="_blank" >10.1007/s10853-015-9646-0</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Static and dynamic characteristics of the Cr3+ EPR spectra in the Van Vleck paramagnet TmAl3(BO3)4

  • Original language description

    The advanced study of Cr3+ impurity ions in the Van Vleck paramagnet TmAl3(BO3)4 is reported in this work. The angular dependence of the electron paramagnetic resonance spectrum from Cr3+ ion has been studied in detail, and the parameters of spin Hamiltonian were evaluated at T = 11 K [g =1.980 0.002; D = (-0.534 0.001) cm-1; E = (0.027 0.005) cm-1]. It was shown that the Cr3+ ions substitute trivalent aluminum ions and form a system of three magnetic equivalent ions rotated through 120 relative to each other. The deviation of the Zaxis from the C3-axis for Cr3+ ions was found to be 2.5. A significant temperature dependence of g and D parameters has been found. It was shown that a strong broadening of the EPR lines depends on the dipole and exchange fields generated by the magnetic moment of the thulium ion.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)

  • CEP classification

    BM - Solid-state physics and magnetism

  • OECD FORD branch

Result continuities

  • Project

    <a href="/en/project/LM2011029" target="_blank" >LM2011029: SAFMAT - Centre of Functional Materials Analyses</a><br>

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2016

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Journal of Materials Science

  • ISSN

    0022-2461

  • e-ISSN

  • Volume of the periodical

    51

  • Issue of the periodical within the volume

    10

  • Country of publishing house

    US - UNITED STATES

  • Number of pages

    7

  • Pages from-to

    4762-4768

  • UT code for WoS article

    000372573000005

  • EID of the result in the Scopus database

    2-s2.0-84959086032