Effect of the substitutional groups on the electrochemistry, kinetic of thermal decomposition and kinetic of substitution of some uranyl Schiff base complexes

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F16%3A00462310" target="_blank" >RIV/68378271:_____/16:00462310 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1007/s13738-016-0807-0" target="_blank" >http://dx.doi.org/10.1007/s13738-016-0807-0</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1007/s13738-016-0807-0" target="_blank" >10.1007/s13738-016-0807-0</a>

Result language
angličtina
Original language name
Effect of the substitutional groups on the electrochemistry, kinetic of thermal decomposition and kinetic of substitution of some uranyl Schiff base complexes
Original language description
Uranyl(VI) complexes [UO2(X-saloph)(solvent)], where saloph denotes N,N’-bis(salicylidene)-1,2-phenylenediamine and X = NO2, Cl, Me, H; were synthesized and characterized by 1H NMR, IR, UV–Vis spectroscopy, thermal gravimetry (TG), cyclic voltammetry, elemental analysis (C.H.N) and X-ray crystallography. The complex of [UO2(4-nitrosaloph)(DMF)] was also synthesized in nano form. The TG method and analysis of Coats-Redfern plots revealed that the kinetics of thermal decomposition of the complexes is of the fistorder in all stages. The kinetics and mechanism of the exchange reaction of the coor dinated solvent with tributylphosphine was investigated by spectrophotometric method. Anticancer properties were also investigated.
Czech name
—
Czech description
—

Type
J<sub>x</sub> - Unclassified - Peer-reviewed scientific article (Jimp, Jsc and Jost)
CEP classification
BM - Solid-state physics and magnetism
OECD FORD branch
—

Project
<a href="/en/project/GA14-03276S" target="_blank" >GA14-03276S: Aspherical effects and their application for statistically correct crystal structure analysis</a><br>
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2016
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Similar results(10)