A novel trinuclear copper(II) complex containing a symmetric tetradentate N2O2 Schiff base ligand: synthesis, characterization, crystal structure and its usage as a new precursor for the preparation of CuO particles

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F17%3A00473782" target="_blank" >RIV/68378271:_____/17:00473782 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1016/j.poly.2016.09.029" target="_blank" >http://dx.doi.org/10.1016/j.poly.2016.09.029</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.poly.2016.09.029" target="_blank" >10.1016/j.poly.2016.09.029</a>

Result language
angličtina
Original language name
A novel trinuclear copper(II) complex containing a symmetric tetradentate N2O2 Schiff base ligand: synthesis, characterization, crystal structure and its usage as a new precursor for the preparation of CuO particles
Original language description
A novel linear centrosymmetric trinuclear copper(II) Schiff base complex with the chemical formula [{Cu (mu-L)(H2O)(mu-NO3)}(2)Cu]center dot H2O, where L = N,N'-bis(2-hydroxy-4-methoxybenzophenone)-2,2-dimethyl-1,3-propanediamine, was synthesized and characterized by elemental analyses, FT-IR spectroscopy, TG-TA and X-ray crystallography. Single X-ray diffraction analysis revealed four mu-phenoxido- and two mu-NO3- bridges in the complex. The equatorial plane of the three linearly arranged copper(II) atoms is formed by oxygen and nitrogen atoms of two anionic tetradentate Schiff base ligands, each of them coordinated to one of the terminal copper(II) ions. The central copper(II) ion is located in an inversion centre and bonded to four pt-oxygen atoms of the same ligand. Thermogravimetric analysis of the complex revealed its thermal stability and decomposition pattern.
Czech name
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Czech description
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Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10401 - Organic chemistry

Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2017
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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