A new inorganic-organic nanohybrid based on a copper(II) semicarbazone complex and the PMo12O3-40 polyanion: synthesis, characterization, crystal structure and photocatalytic activity for degradation of cationic dyes

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F17%3A00473806" target="_blank" >RIV/68378271:_____/17:00473806 - isvavai.cz</a>
Result on the web
<a href="https://doi.org/10.1016/j.poly.2016.11.034" target="_blank" >https://doi.org/10.1016/j.poly.2016.11.034</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.poly.2016.11.034" target="_blank" >10.1016/j.poly.2016.11.034</a>

Result language
angličtina
Original language name
A new inorganic-organic nanohybrid based on a copper(II) semicarbazone complex and the PMo12O3-40 polyanion: synthesis, characterization, crystal structure and photocatalytic activity for degradation of cationic dyes
Original language description
A new inorganic-organic nanohybrid based on a Keggin-type polyoxornolybdate and a copper(II) semicarbazone complex, namely [Cu-2(HL)(2)(PMo12O40)(OCH3)(2)(Cl)(H2O)]center dot 8CH(3)OH center dot 4H(2)O [HL= pyridine-2-carbaldehyde semicarbazone] (1) was synthesized by a sonochemical method. Single crystals of 1 were synthesized with the branched tube method. The nanohybrid 1 was characterized using FT-IR, PXRD, FESEM, TEM, EDX, UV-Vis, TG-DTA analysis and single-crystal X-ray diffraction. Single-crystal X-ray diffraction reveals that the PMo12O403- cluster acts as a bidentate inorganic ligand and coordinates two symmetrically equivalent [Cu(Cl)(0.5)(HL)(OCH3)(H2O)(0.5)] complexes. SEM and TEM images confirmed a highly porous plate-like morphology of the nanohybrid sample. To the best of our knowledge, 1 represents the first example of a hybrid based on POMs and semicarbazone Schiff base complexes.
Czech name
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Czech description
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Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10402 - Inorganic and nuclear chemistry

Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2017
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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