Donor-acceptor properties of a single-molecule altered by on-surface complex formation
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F17%3A00484817" target="_blank" >RIV/68378271:_____/17:00484817 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1021/acsnano.7b03954" target="_blank" >http://dx.doi.org/10.1021/acsnano.7b03954</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/acsnano.7b03954" target="_blank" >10.1021/acsnano.7b03954</a>
Alternative languages
Result language
angličtina
Original language name
Donor-acceptor properties of a single-molecule altered by on-surface complex formation
Original language description
Electron donor acceptor molecules are of outstanding interest in molecular electronics and organic solar cells for their intramolecular charge transfer controlled via electrical or optical excitation. The preservation of their electronic character in the ground state upon adsorption on a surface is cardinal for their implementation in such single molecule devices. Here, we investigate by atomic force microscopy and scanning tunneling microscopy a prototypical system consisting of a pi-conjugated tetrathiafulvalene-fused dipyridophenazine molecule adsorbed on thin NaCl films on Cu(111). Depending on the adsorption site, the molecule is found either in a nearly undisturbed free state or in a bound state. In the latter case, the molecule adopts a specific adsorption site, leading to the formation of a chelate complex with a single Na+ alkali cation pulled out from the insulating film.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10302 - Condensed matter physics (including formerly solid state physics, supercond.)
Result continuities
Project
<a href="/en/project/GB14-37427G" target="_blank" >GB14-37427G: Center of spintronics</a><br>
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2017
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
ACS Nano
ISSN
1936-0851
e-ISSN
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Volume of the periodical
11
Issue of the periodical within the volume
8
Country of publishing house
US - UNITED STATES
Number of pages
8
Pages from-to
8413-8420
UT code for WoS article
000408520900095
EID of the result in the Scopus database
2-s2.0-85028470393