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Optical revelation of defects in epitaxial barium titanate films

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F19%3A00505522" target="_blank" >RIV/68378271:_____/19:00505522 - isvavai.cz</a>

  • Result on the web

    <a href="http://hdl.handle.net/11104/0297008" target="_blank" >http://hdl.handle.net/11104/0297008</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1039/c9cp00923j" target="_blank" >10.1039/c9cp00923j</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Optical revelation of defects in epitaxial barium titanate films

  • Original language description

    Allying epitaxial strain and synthesis conditions allows for the introduction of specific point defects in perovskite oxide films. In ferroelectric films, such defects lead to essential polar and electronic properties, which can enable advanced applications. Here, to elucidate the nature of the defects, optical constants are investigated in the spectral range of 0.7–8.8 eV in epitaxial ferroelectric BaTiO3 films, which are synthesized under different conditions. It is demonstrated that oxygen-vacancy-related defects are responsible for a peculiar transition below the bandgap at B2.7–2.9 eV and significant blueshifts of B0.3–0.4 eV of the gap and the main interband transitions. These observations suggest that the defects are dipolar complexes comprising titanium cations and oxygen vacancies (Ti3+–VO).

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10302 - Condensed matter physics (including formerly solid state physics, supercond.)

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2019

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Physical Chemistry Chemical Physics

  • ISSN

    1463-9076

  • e-ISSN

  • Volume of the periodical

    21

  • Issue of the periodical within the volume

    15

  • Country of publishing house

    GB - UNITED KINGDOM

  • Number of pages

    5

  • Pages from-to

    7874-7878

  • UT code for WoS article

    000465260400015

  • EID of the result in the Scopus database

    2-s2.0-85064214194