Synthesis of new bipyridine N,N,-dioxides and their application in asymmetric allylation of benzaldehyde and aldol addition to acetophenone

Result code in IS VaVaI

<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F19%3A00518983" target="_blank" >RIV/68378271:_____/19:00518983 - isvavai.cz</a>

Alternative codes found

RIV/00216208:11310/19:10393755

Result on the web

<a href="https://doi.org/10.1007/s00706-018-2289-5" target="_blank" >https://doi.org/10.1007/s00706-018-2289-5</a>

DOI - Digital Object Identifier

<a href="http://dx.doi.org/10.1007/s00706-018-2289-5" target="_blank" >10.1007/s00706-018-2289-5</a>

Result language

angličtina

Original language name

Synthesis of new bipyridine N,N,-dioxides and their application in asymmetric allylation of benzaldehyde and aldol addition to acetophenone

Original language description

Chiral pyridine N-oxides and bipyridine N,N´-dioxides are an important class of heteroaromatic compounds with interesting chemical properties. Polarization of the N–O bond results in their electron-donation activity and makes them rather strong Lewis bases, which are able to activate Lewis acids such as trichlorosilanes. Therefore, they can catalyze a number of various reactions such as allylation and crotylation of aldehydes, aldol reactions, ring-opening of epoxides, and cyanosilylation of ketones and imides. Due to the general high interest in the development of new Lewis basic chiral organocatalysts, synthetic approaches providing new chiral compounds possessing the pyridine N-oxide moiety are desirable.n

Czech name

—

Czech description

—

Type

J_imp - Article in a specialist periodical, which is included in the Web of Science database

CEP classification

—

OECD FORD branch

10302 - Condensed matter physics (including formerly solid state physics, supercond.)

Project

<a href="/en/project/GA17-07707S" target="_blank" >GA17-07707S: Development of New Syntheses of Azaheterocycles</a><br>

Continuities

I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year

2019

Confidentiality

S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Name of the periodical

Monatshefte fur Chemie

ISSN

0026-9247

e-ISSN

—

Volume of the periodical

150

Issue of the periodical within the volume

1

Country of publishing house

AT - AUSTRIA

Number of pages

20

Pages from-to

29-48

UT code for WoS article

000454953600005

EID of the result in the Scopus database

2-s2.0-85056640511