Interface dipoles of Ir(ppy)3 on Cu(111)
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F19%3A00521231" target="_blank" >RIV/68378271:_____/19:00521231 - isvavai.cz</a>
Alternative codes found
RIV/61989592:15310/19:73598020
Result on the web
<a href="https://doi.org/10.1039/c9nr00934e" target="_blank" >https://doi.org/10.1039/c9nr00934e</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/c9nr00934e" target="_blank" >10.1039/c9nr00934e</a>
Alternative languages
Result language
angličtina
Original language name
Interface dipoles of Ir(ppy)3 on Cu(111)
Original language description
The interplay of adsorption geometry and interface dipoles of the transition-metal complex Ir(ppy)3 on Cu(111) was studied using low-temperature scanning probe microscopy and density-functional-theory calculations. We find that the orientation of the molecule's intrinsic dipole moment with respect to the surface has a strong influence on the total energy of the different configurations, where the most stable one has the molecular dipole moment pointing out of the surface plane along the surface normal. Adsorption-induced redistribution of charges results in an additional dipole moment that also points out of the surface plane for all configurations. Submolecularly resolved maps of the resulting local contact potential difference suggest that any in-plane dipole moment is very effectively screened.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10302 - Condensed matter physics (including formerly solid state physics, supercond.)
Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)
Others
Publication year
2019
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Nanoscale
ISSN
2040-3364
e-ISSN
—
Volume of the periodical
11
Issue of the periodical within the volume
26
Country of publishing house
GB - UNITED KINGDOM
Number of pages
9
Pages from-to
12695-12703
UT code for WoS article
000474160000028
EID of the result in the Scopus database
2-s2.0-85068519890