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Full crystal structure, hydrogen bonding and spectroscopic, mechanical and thermodynamic properties of mineral uranopilite

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F20%3A00535138" target="_blank" >RIV/68378271:_____/20:00535138 - isvavai.cz</a>

  • Alternative codes found

    RIV/00023272:_____/20:10134908

  • Result on the web

    <a href="https://doi.org/10.1039/d0ra04596a" target="_blank" >https://doi.org/10.1039/d0ra04596a</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1039/d0ra04596a" target="_blank" >10.1039/d0ra04596a</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Full crystal structure, hydrogen bonding and spectroscopic, mechanical and thermodynamic properties of mineral uranopilite

  • Original language description

    The determination of the full crystal structure of the uranyl sulfate mineral uranopilite, (UO2)6(SO4)O2(OH)6.14H2O, including the positions of the hydrogen atoms within the corresponding unit cell, has not been feasible to date due to the poor quality of its X-ray diffraction pattern. In this paper, the complete crystal structure of uranopilite is established for the first time by means of first principles solid-state calculations based in density functional theory employing a large plane wave basis set and pseudopotential functions. The computed unit-cell parameters and structural data for the non-hydrogen atoms are in excellent agreement with the available experimental data. The computed X-ray diffraction pattern is also in satisfactory agreement with the experimental pattern.n

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10504 - Mineralogy

Result continuities

  • Project

    <a href="/en/project/GA20-11949S" target="_blank" >GA20-11949S: UNanoCryst: crystallography and mineralogy of supergene weathering products of uraninite at the nanoscale</a><br>

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2020

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    RSC Advances

  • ISSN

    2046-2069

  • e-ISSN

  • Volume of the periodical

    10

  • Issue of the periodical within the volume

    53

  • Country of publishing house

    GB - UNITED KINGDOM

  • Number of pages

    14

  • Pages from-to

    31947-31960

  • UT code for WoS article

    000565206400031

  • EID of the result in the Scopus database

    2-s2.0-85090947121