Broad-band spectroscopy of nanoconfined water molecules
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F20%3A00536076" target="_blank" >RIV/68378271:_____/20:00536076 - isvavai.cz</a>
Result on the web
<a href="http://dx.doi.org/10.1007/978-3-030-31866-6_2" target="_blank" >http://dx.doi.org/10.1007/978-3-030-31866-6_2</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1007/978-3-030-31866-6_2" target="_blank" >10.1007/978-3-030-31866-6_2</a>
Alternative languages
Result language
angličtina
Original language name
Broad-band spectroscopy of nanoconfined water molecules
Original language description
We have performed broad-band spectroscopic investigations of vibrational and relaxational excitations of water molecules confined to nanocages within artificial beryl and mineral cordierite crystals. Signatures of quantum critical phenomena within the H2O molecular network are registered in beryl. In cordierite, a density functional analysis is applied to reconstruct the potential energy landscape experienced by H2O molecules, revealing a pronounced anisotropy with a potential well of about 10 meV for the molecular dipole moment aligned along the b-axis.This anisotropy leads to a strongly temperature dependent and anisotropic relaxational response of the dipoles at radiofrequencies with the activation energies corresponding to the barriers of the rotational potential. At T≈3 K, we identify signatures of a transition onto a glassy state composed by clusters of H2O dipoles.n
Czech name
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Czech description
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Classification
Type
D - Article in proceedings
CEP classification
—
OECD FORD branch
10302 - Condensed matter physics (including formerly solid state physics, supercond.)
Result continuities
Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2020
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Article name in the collection
IFMBE Proceedings
ISBN
978-3-030-31865-9
ISSN
1680-0737
e-ISSN
—
Number of pages
5
Pages from-to
7-11
Publisher name
Springer International Publishing
Place of publication
New York
Event location
Chisinau
Event date
Sep 18, 2019
Type of event by nationality
WRD - Celosvětová akce
UT code for WoS article
000552314200002