Formation of a copper-copper bond in coordination of a cyclotriphosphazene ligand toward Cu(II): Structural, spectral and docking studies

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F20%3A00537792" target="_blank" >RIV/68378271:_____/20:00537792 - isvavai.cz</a>
Result on the web
<a href="https://doi.org/10.1016/j.molstruc.2020.127804" target="_blank" >https://doi.org/10.1016/j.molstruc.2020.127804</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.molstruc.2020.127804" target="_blank" >10.1016/j.molstruc.2020.127804</a>

Result language
angličtina
Original language name
Formation of a copper-copper bond in coordination of a cyclotriphosphazene ligand toward Cu(II): Structural, spectral and docking studies
Original language description
Two cyclotriphosphazene compounds, [HMPAP]2[SO4].2CH3OH (1), and [Cu(μ-OAc)2(MPAP)]2 (2), were prepared and identified by elemental analysis, FT-IR, Raman spectroscopy and single-crystal X-ray diffraction. In the crystal structure of 1, one nitrogen atom of the cyclotriphosphazene ring has been protonated. The copper complex (2) is binuclear formed by four bridging acetato ligands containing one Cu-Cu bond in the center of the complex. Each copper atom has a Cu(O4NCu) environment with octahedral geometry which is distorted owing to the Jahn-Teller effect. In the crystal network of the compounds, in addition to hydrogen bonds and hydrogen bond motifs (only in 1), p-p stacking interactions between phenyl rings further stabilize the crystal network.n
Czech name
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Czech description
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Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10302 - Condensed matter physics (including formerly solid state physics, supercond.)

Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2020
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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