Synthesis and structural characterization of phosphinate coordination polymers with tin(IV) and copper(II)

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F20%3A00537795" target="_blank" >RIV/68378271:_____/20:00537795 - isvavai.cz</a>
Result on the web
<a href="https://doi.org/10.1016/j.molstruc.2019.127369" target="_blank" >https://doi.org/10.1016/j.molstruc.2019.127369</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1016/j.molstruc.2019.127369" target="_blank" >10.1016/j.molstruc.2019.127369</a>

Result language
angličtina
Original language name
Synthesis and structural characterization of phosphinate coordination polymers with tin(IV) and copper(II)
Original language description
In this work, we report the synthesis and X-ray characterization of diphenylphosphinic acid (L) and its two polymeric phosphinate complexes, [(C6H5)2P(O)OSn(C6H5)3]n (C1) and [Cu(O2PPh2)2]n (C2), resulted from the bidentate coordinatioan of L. Sn(IV) centers in C1 are five-coordinate in a distorted trigonal bipyramidal geometry. One dimensional coordination chains of C2 are made by double-bridging ligands between the copper atoms, surrounded with four P-O in a square planar polyhedron. Structural characterization of the complexes revealed that M-O bonds are responsible for the assembly of the pri mary structural motifs in both the complexes while C-H … p and H/H interactions are effective in organizing these molecules into extended 3D architectures. The quantitative mapping of interactions was also analyzed using Hirshfeld surface analysis.
Czech name
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Czech description
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Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10302 - Condensed matter physics (including formerly solid state physics, supercond.)

Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Publication year
2020
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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