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Correlation of emission, scintillation and charge trapping properties in Cs2HfCl6 and Cs2ZrCl6 single crystals

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F21%3A00541724" target="_blank" >RIV/68378271:_____/21:00541724 - isvavai.cz</a>

  • Alternative codes found

    RIV/68407700:21340/21:00350454

  • Result on the web

    <a href="https://doi.org/10.1039/d0tc05482h" target="_blank" >https://doi.org/10.1039/d0tc05482h</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1039/d0tc05482h" target="_blank" >10.1039/d0tc05482h</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Correlation of emission, scintillation and charge trapping properties in Cs2HfCl6 and Cs2ZrCl6 single crystals

  • Original language description

    The temperature dependence of the scintillation light output exhibits an unusual s-shaped character with the drop at around 100 K that correlates well with the decrease in the Vk(a) EPR signal, evidencing detrapping of holes trapped at the Vk(a) center in the Cs2(a)HfCl6 (CHC) crystal. Therefore, the Vk(a) center was assumed to be the part of Hf3+–Cl2- self-trapped exciton (STE) that participates in the emission above 100 K becoming ‘‘frozen’’ below 100 K. RL and TSL spectra were complex in the CHC sample composed of two and three overlapping bands, respectively. One of the components peaking at 2.65 eV originated from the Zr-related STE.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10302 - Condensed matter physics (including formerly solid state physics, supercond.)

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Others

  • Publication year

    2021

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Journal of Materials Chemistry C

  • ISSN

    2050-7526

  • e-ISSN

    2050-7534

  • Volume of the periodical

    9

  • Issue of the periodical within the volume

    8

  • Country of publishing house

    GB - UNITED KINGDOM

  • Number of pages

    14

  • Pages from-to

    2955-2968

  • UT code for WoS article

    000625555700036

  • EID of the result in the Scopus database

    2-s2.0-85102047854