Design and self-assembling behaviour of calamitic reactive mesogens with lateral methyl and methoxy substituents and vinyl terminal group

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F21%3A00543634" target="_blank" >RIV/68378271:_____/21:00543634 - isvavai.cz</a>
Result on the web
<a href="http://hdl.handle.net/11104/0320837" target="_blank" >http://hdl.handle.net/11104/0320837</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.3390/polym13132156" target="_blank" >10.3390/polym13132156</a>

Result language
angličtina
Original language name
Design and self-assembling behaviour of calamitic reactive mesogens with lateral methyl and methoxy substituents and vinyl terminal group
Original language description
In order to control and stabilize the liquid crystalline behaviour, and hence the self-organization, the polymerization process can be effectively used. Mesogenic units incorporated into the backbones as functional side-chains of weakly cross-linked macromolecules can become orientationally ordered. Several new calamitic reactive mesogens possessing the vinyl terminal group with varying flexible chain lengths and with/without lateral substitution by the methyl (methoxy) groups have been designed and studied. Depending on molecular structure, namely the type and position of lateral substituents, the resulting materials possess the nematic, the orthogonal SmA and the tilted SmC phases structure of mesophases was confirmed by SAXS. The main objective of this work is to contribute to better understanding of molecular structure – mesomorphic property relationship for new functional reactive mesogens aimed for further design of smart self-organizing macromolecular materials.n
Czech name
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Czech description
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Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
21002 - Nano-processes (applications on nano-scale); (biomaterials to be 2.9)

Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2021
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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