Tl0.6Mo3S5, an original large tunnel-like molybdenum sulfide with Mo zigzag chains and disordered Tl cations

Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F21%3A00546393" target="_blank" >RIV/68378271:_____/21:00546393 - isvavai.cz</a>
Result on the web
<a href="http://hdl.handle.net/11104/0323213" target="_blank" >http://hdl.handle.net/11104/0323213</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1039/D1MA00568E" target="_blank" >10.1039/D1MA00568E</a>

Result language
angličtina
Original language name
Tl0.6Mo3S5, an original large tunnel-like molybdenum sulfide with Mo zigzag chains and disordered Tl cations
Original language description
We report on the crystal structure and physical properties of Tl0.6Mo3S5, which belongs to a novel family of materials with large tunnels, reminiscent of those observed in the romanechite structure type. Tl cations are partially filling these tunnels delimited by the Mo–S cluster framework in which the Mo atoms form infinite zigzag chains. Single-crystal X-ray diffraction data indicate that this compound crystallizes in the monoclinic, non-centrosymmetric space group P21 (no. 4, a = 9.344(2) Å, b = 3.234(2) Å, c = 11.669(2) Å and β = 113.09(2)° at 293 K).
Czech name
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Czech description
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Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10302 - Condensed matter physics (including formerly solid state physics, supercond.)

Project
Result was created during the realization of more than one project. More information in the Projects tab.
Continuities
P - Projekt vyzkumu a vyvoje financovany z verejnych zdroju (s odkazem do CEP)

Publication year
2021
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

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