Autocatalytic surface explosion chemistry of 2D metal-organic frameworks
The result's identifiers
Result code in IS VaVaI
<a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F21%3A00549996" target="_blank" >RIV/68378271:_____/21:00549996 - isvavai.cz</a>
Result on the web
<a href="https://doi.org/10.1021/acs.jpcc.1c03809" target="_blank" >https://doi.org/10.1021/acs.jpcc.1c03809</a>
DOI - Digital Object Identifier
<a href="http://dx.doi.org/10.1021/acs.jpcc.1c03809" target="_blank" >10.1021/acs.jpcc.1c03809</a>
Alternative languages
Result language
angličtina
Original language name
Autocatalytic surface explosion chemistry of 2D metal-organic frameworks
Original language description
Metal–organic frameworks are a combination of inorganic constituents and organic ligands with a high degree of variability which are, as coordination compounds in homogeneous catalysis, potentially highly selective heterogeneous catalysts. The synthesis and thermal stability of monolayer thin Cu-, Ni-, and Fe-squarate 2D MOFs are studied using X-ray photoelectron spectroscopy, scanning tunneling microscopy, and temperature-programmed reaction spectroscopy on a Cu(100) surface in ultrahigh vacuum. Highly ordered 2D squarate MOFs are obtained by mild annealing of squarate multilayers. Upon annealing at higher temperatures, the Ni- and Fe-squarate layers undergo autocatalytic surface explosion chemistry with carbon monoxide as a desorbing product in a very narrow temperature interval. Despite the different stabilities of Ni- and Fe-based MOFs, mixed {Ni + Fe}-MOFs also decompose in a narrow single temperature interval.
Czech name
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Czech description
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Classification
Type
J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database
CEP classification
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OECD FORD branch
10302 - Condensed matter physics (including formerly solid state physics, supercond.)
Result continuities
Project
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Continuities
I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace
Others
Publication year
2021
Confidentiality
S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů
Data specific for result type
Name of the periodical
Journal of Physical Chemistry C
ISSN
1932-7447
e-ISSN
1932-7455
Volume of the periodical
125
Issue of the periodical within the volume
24
Country of publishing house
US - UNITED STATES
Number of pages
7
Pages from-to
13343-13349
UT code for WoS article
000668350500026
EID of the result in the Scopus database
2-s2.0-85108868805