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Crystal structure evolution in the van der Waals vanadium trihalides

The result's identifiers

  • Result code in IS VaVaI

    <a href="https://www.isvavai.cz/riv?ss=detail&h=RIV%2F68378271%3A_____%2F22%3A00557986" target="_blank" >RIV/68378271:_____/22:00557986 - isvavai.cz</a>

  • Alternative codes found

    RIV/00216208:11320/22:10444419

  • Result on the web

    <a href="https://doi.org/10.1088/1361-648X/ac6d38" target="_blank" >https://doi.org/10.1088/1361-648X/ac6d38</a>

  • DOI - Digital Object Identifier

    <a href="http://dx.doi.org/10.1088/1361-648X/ac6d38" target="_blank" >10.1088/1361-648X/ac6d38</a>

Alternative languages

  • Result language

    angličtina

  • Original language name

    Crystal structure evolution in the van der Waals vanadium trihalides

  • Original language description

    Most transition-metal trihalides are dimorphic. The representative chromium-based triad, CrCl3, CrBr3, CrI3, is characterized by the low-temperature (LT) phase adopting the trigonal BiI3-type while the structure of the high-temperature (HT) phase is monoclinic of AlCl3 type (C2/m). The structural transition between the two crystallographic phases is of the first-order type with large thermal hysteresis in CrCl3 and CrI3. We studied crystal structures and structural phase transitions of vanadium-based counterparts VCl3, VBr3, and VI3 by measuring specific heat, magnetization, and x-ray diffraction as functions of temperature and observed an inverse situation.

  • Czech name

  • Czech description

Classification

  • Type

    J<sub>imp</sub> - Article in a specialist periodical, which is included in the Web of Science database

  • CEP classification

  • OECD FORD branch

    10302 - Condensed matter physics (including formerly solid state physics, supercond.)

Result continuities

  • Project

    Result was created during the realization of more than one project. More information in the Projects tab.

  • Continuities

    I - Institucionalni podpora na dlouhodoby koncepcni rozvoj vyzkumne organizace

Others

  • Publication year

    2022

  • Confidentiality

    S - Úplné a pravdivé údaje o projektu nepodléhají ochraně podle zvláštních právních předpisů

Data specific for result type

  • Name of the periodical

    Journal of Physics-Condensed Matter

  • ISSN

    0953-8984

  • e-ISSN

    1361-648X

  • Volume of the periodical

    34

  • Issue of the periodical within the volume

    29

  • Country of publishing house

    GB - UNITED KINGDOM

  • Number of pages

    8

  • Pages from-to

    294007

  • UT code for WoS article

    000798965000001

  • EID of the result in the Scopus database

    2-s2.0-85130863715